{"product_id":"9783709117354","title":"Material Designs and New Physical Properties in MX- and MMX-Chain Compounds","description":"\u003ch1\u003eMaterial Designs and New Physical Properties in MX- and MMX-Chain Compounds\u003c\/h1\u003e \u003ch2\u003eYamashita, Masahiro; Okamoto, Hiroshi\u003c\/h2\u003e \u003cp\u003e\u003c\/p\u003e\u003cp\u003eThis is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.\u003c\/p\u003e \u003ch3\u003eDetails\u003c\/h3\u003e \u003cp\u003ePublished by: Springer\u003c\/p\u003e \u003cp\u003ePublication Date: 2015-01-29\u003c\/p\u003e \u003cp\u003eFormat: Paperback\u003c\/p\u003e \u003cp\u003eISBN-13: 9783709117354\u003c\/p\u003e \u003cp\u003eDOI: 10.1007\/978-3-7091-1317-2\u003c\/p\u003e \u003cp\u003eDimensions: 235cm x155cm\u003c\/p\u003e \u003cp\u003ePages: 270\u003c\/p\u003e ","brand":"Springer Vienna","offers":[{"title":"Default Title","offer_id":49940185907340,"sku":"9783709117354","price":98.99,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0710\/9545\/1788\/files\/9783709117354.jpg?v=1779056455","url":"https:\/\/fh90cf-fv.myshopify.com\/products\/9783709117354","provider":"Late Knight Books and Services, LLC","version":"1.0","type":"link"}